Palladium-catalyzed homocoupling reactions between two Csp(3)-Csp(3) centers.
نویسندگان
چکیده
[reaction: see text] A novel palladium-catalyzed coupling reaction between two Csp(3)-Csp(3) centers has been investigated. This protocol is initiated by the oxidative addition of an alpha-halo carbonyl compound to a palladium(0) species, followed by the double transmetalation. The key dialkyl palladium intermediate undergoes reductive elimination to form the desired coupling product.
منابع مشابه
Pii: S0040-4039(02)00328-3
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ورودعنوان ژورنال:
- Organic letters
دوره 4 14 شماره
صفحات -
تاریخ انتشار 2002